First woman villain (Klebb was working for Bolfeld and therefore he was the villain in From Russia With Love)
First time Bond gets a semi-serious injury (dislocated collarbone)
First time MI6 goes to Scotland
First time Tanner and Robinson are in a movie together (Tanner is from Fleming's original novels as well as numerous movies over the years and Robinson is from Tomorrow Never Dies)
First time M is captured
First time M sees Bond kill in cold blood
First time M slaps someone
First time M kisses someone (King)
First time Q considers retiring
First bomb explosion inside MI6 Headquarters
First time 007 is on the inactive list
First terrorist attack at MI6 Headquarters
First time Bond shoots a woman in cold blood
First time 007 holds a Colt .45 Automatic handgun
First appearance of a woman with a mangled physical feature (Electra's earlobe)
First time a woman seeks retribution against MI6
First time 007 goes to Azerbaijan
First time a Bond girl is a nuclear physicist (Denise Richards)
First villain with a bullet in his skull (Robert Carlyle)
First time where deforestation is depicted in a Bond film
First time Bond's gun explodes
First time portrait of M (Bernard Lee) appears in Bond movie. In conference room of MI6 headquarters when Electra appears on two wall video screens the portrait of M can be seen between them.
First time the credit sequence doesn't go: Bond, Bond Girl, Bond Villain, Rest of cast (Denise Richards is 4th)
First chase sequence through the River Thames
First appearance of John Cleese as Q's assistant
First time Bond is the first thing on screen after the gunbarrel opening
First movie to show a female 00 agent in the scene where Bond is excluded from receiving an assignment. This is assuming that the people seated and standing around him are other 00's.
First time 007 goes to a casino and doesnt gamble
First time Bond made love to the villain
First Brosnan film that didn't have Jack Wade in it
First Brosnan film that didn't have an Aston Martin driven by Bond
First time Bond killed one of his lovers
First time Bond is tortured
First time bond has to deal with terrorists
First living henchman with a bullet in his head
First time there is the involvement of oil
First time a pipeline is shown in a Bond film
First time an element from a non-Fleming book is incorporated into the story (Kingsley Amis wrote Colonel Sun, in which M is kidnapped, like in this film)
Dr. No
From Russia With Love
Goldfinger
Thunderball
You Only Live
Twice
On Her Majesty's
Secret Service
Diamonds Are
Forever
Live and Let Die
The Man With
the Golden Gun
The Spy Who
Loved Me
Moonraker
For Your Eyes
Only
Octopussy
A View to a Kill
The Living Daylights
Licence to Kill
GoldenEye
Tomorrow
Never Dies
The World is NotEnough
Die Another
Day
Casino Royale
Quantum of
Solace 
Skyfall 
SPECTRE
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